scf-PILA

Production Scientifique RAPSODEE

2009-04-20T09:00:13+00:00

Wang Y, Wei D, Dave R, Pfeffer R, Sauceau M, Letourneau JJ and Fages J.
Extraction and Precipitation Particle Coating Using Supercritical CO2.
Powder Technol. 2002, 127, p. 32-44

Sauceau M, Letourneau JJ, Richon D and Fages J.
Enhanced density-based models for solid compound solubilities in supercritical carbon dioxide with cosolvents.
Fluid Phase Equilib., 2003, 208, p. 99-113

Fages J, Lochard H, Rodier E, Letourneau JJ et Sauceau M.
La G�n�ration de Solides Divis�s par Fluides Supercritiques.
Can. J. Chem. Eng., 2003, 81, p. 161-175

Sauceau M, Letourneau JJ, Freiss B, Richon D and Fages J.
Solubility of eflucimibe in supercritical carbon dioxide with or without a co-solvent.
J. Supercrit. Fluids., 2004, 31, p. 133-140

Fages J, Lochard H, Letourneau JJ, Sauceau M and Rodier E.
Particle Generation for Pharmaceutical Applications Using Supercritical Fluid Technology.
Powder Technol., 2004, 141, p. 219-226

Letourneau JJ, Vigneau S, Gonus P and Fages J.
Micronized cocoa butter particles produced by a supercritical process.
Chem Eng. Proc., 2005, 44, p. 201-207

Fages J., Letourneau J.-J., Sauceau M., Rodier E.
�laboration de Solides Divis�s par Fluide Supercritique.
Techniques de l�Ing�nieur, Trait� Recherche et Innovation RE26. 2005, p. 1-12.

Rodier E., Lochard H., Sauceau M., Letourneau JJ, Freiss B. and Fages J.
A three-step supercritical process to improve the dissolution rate of Eflucimibe.
Eur. J. Pharm. Sci., 2005, 26, p. 184-193

Sampaio de Sousa AR, Calderone M, Rodier E, Fages J, and Duarte C.M.M.
Solubility of carbon dioxide in three lipid-based biocarriers.
J. Supercrit. Fluids. 2006. 39 (1) : 13-19

Calderone M, Rodier E and Fages J.
Microencapsulation by a Solvent-Free Supercritical Fluid Process: Use of Density, Calorimetric and Size Analysis to Quantify and Qualify the Coating.
Particle Sci. Technol. 2007. 25(3) : 215-225

Bounaceur A, Rodier E and Fages J.
Maturation of a ketoprofen/beta-cyclodextrin mixture, with supercritical carbon dioxide.
J. Supercrit. Fluids. 2007. 41(3): 429-439

Calderone M, Rodier E, Letourneau JJ and Fages J.
Solidification of Precirol(r) by the expansion of a supercritical fluid saturated melt: from the thermodynamic balance towards the crystallization aspect. J.
Supercrit. Fluids. 2007.42 (2) : 189�199

Sauceau M, Nikitine C, Rodier E, and Fages J.
Effect of Supercritical Carbon Dioxide on Polystyrene Extrusion.
J. Supercrit. Fluids.2007. 43 : 367-373

Fages J, , Rodier E, Chamayou A and Baron M.
Comparative study of two processes to improve the bioavailability of an active pharmaceutical ingredient: kneading and supercritical technology.
Kona.2007. 25 : 217-229.

Calderone M, Rodier E, Lochard H, Marciacq F and Fages J.
A new supercritical co-injection process to coat microparticles.
Chem. Eng. Proc. 2008.47 (12) : 2228-2237

Sauceau M, Rodier E and Fages J.
Preparation of Inclusion Complex of Piroxicam with Cyclodextrin by Using Supercritical Carbon Dioxide.
J. Supercrit. Fluids. 2008. 47(2) : 327-332

Nikitine C, Rodier E, Sauceau M and Fages J.
Residence time distribution of a pharmaceutical grade polymer/supercritical CO2 melt in a single screw extrusion process.
Chem. Eng. Res. Des. In press 2009.

Contacts

2009-04-20T08:53:52+00:00

Directeurs

Alain de Ryck

Contact : Jacques FAGES

Adresse

RAPSODEE
Ecole des Mines 81013 ALBI cedex 9

T�l

05 63 49 30 07

Fax

05 63 49 30 25

Email

Jacques.Fages@enstimac.fr

Site Web

http://www.enstimac.fr/recherche/rapsodee

Th�matiques

2008-11-28T09:42:31+00:00

Elaboration et mise en forme de mat�riaux finement divis�s: �quipements de cristallisation par spray ou en r�acteur agit� (cristallisoirs �quip�s de fen�tres saphir)
Emulsification, dispersion, encapsulation: encapsulation/enrobage par spray ou en r�acteur agit�

Extraction / Impr�gnation / Nettoyage: �quipement d�infiltration en batch ou semi-continu

Extrusion assist�e par fluide supercritique: formation de microfibres de polym�res par technique d�antisolvant

Mesure et mod�lisation de la solubilit� en FSC: technique du point de pr�cipitation dans une cellule saphir agit�e et � volume variable

Simulation des r�acteurs � l��chelle macroscopique: m�canique des fluides appliqu�e au proc�d� de cristallisation

Production Scientifique TREFLE

2008-11-28T09:37:44+00:00

S. Laugier, D. Richon, F. Rivollet
New volume translation for cubic equation of state
Fluid Phase Equilibria 259 (2007) 99-104

A. Vega-Gonzalez, P. Marteau, P. Subra-Paternault
Monitoring a crystallization induced by compressed CO2 with Raman spectroscopy
AIChE J. 52 (2006) 1308-1317

A. R. Duarte, C. Roy, A. Vega-Gonzalez, C. Duarte, P. Subra-Paternault
Preparation of acetazolamide composite microparticles by supercritical antisolvent techniques
Int. J. of Pharmaceutics 332 (2007) 132-139

S. Diankov, D. Barth, A. Vega-Gonzalez, I. Pentchev, P. Subra-Paternault
Impregnation isotherms of hydroxybenzoic acid on PMMA in supercritical carbon dioxide
J. Supercrit. Fluids, 41 (2007),� 164-172

P. Subra-Paternault, C. Roy, A. Vega-Gonzalez, C. Domingo
Solvent effect on tolbutamide crystallization induced by compressed CO2 as antisolvent
Journal of Crystal GrowthVolume 309 ( 2007) 76-85

C. Roy, A. Vega-Gonz�lez, P. Subra-Paternault
Theophylline formulation by supercritical antisolvents
Int. J. Pharmaceutics vol 343 (2007) 79-89

P. Subra-Paternault, Ch. Roy, A. Vega-Gonzalez, P. Jestin
Crystallization of drugs using supercritical CO2 as antisolvent�: from phase equilibria to products Intern
J. Chem. Reactor Eng. Vol 5 (2007) A45

A. Vega-Gonzalez, P.Subra-Paternault, A. Lopez-Periago, C. Garcia-Gonzalez, C. Domingo
Supercritical CO2 antisolvent precipitation of polymer networks of l-PLA, PMMA and PMMA-PCL blends for biomedical applications
European Polymer Journal 44 (2008) 1081-1094

Contacts

2008-11-05T11:10:43+00:00

Directeur

Jean-Rodolphe PUIGGALI

Contact

P. Subra-Paternault

Adresse

Laboratoire Transferts-Ecoulements-Fluides-Energ�tiques (TREFLE)
UMR 5629 ENSAM-CNRS-Universit� Bordeaux 1
Esplanade des Arts et M�tiers, 33 405 Talence Cedex

T�l

05 40 00 27 03

Fax

05 56 84 54 36

Email

subra@enscpb.fr

Th�matiques

2008-06-11T12:39:42+00:00

Proc�d�s et r�actions en milieu supercritique

Extraction / Impr�gnation / Nettoyage

Production Scientifique LCA

2008-06-11T12:33:18+00:00

C. Vieville, Z. Mouloungui, A. Gaset,
Esterification of oleic acid by methanol catalyzed by p-toluene sulfonic acid and the cation exchange resins K 2411 and K 1481 in supercritical carbon dioxide
Industrial & Engineering Chemistry Research, 1993, 32(9), p 2065-2068.

C. Vieville, Z. Mouloungui, A. Gaset,
Kinetics of the oleic acid esterification by methanol in the presence of solid acid catalysts in supercritical carbon dioxide,
Proceedings of the 3rd International Symposium Supercritic. Fluids, 3, 19-24, 1994

C. Vieville, Z. Mouloungui, A. Gaset ,
Kinetics of the oleic acid esterification by methanol in the presence of solid acid catalysts in supercritical carbon dioxide (full paper),
Third International Symposium on Supercritical Fluids, Strasbourg (France), 17-19 Octobre 1994

C. Vieville, Z. Mouloungui, A. Gaset,
Influence de la pression sur la mise en �uvre de l'est�rification acido-catalys�e de l'acide ol�ique par le m�thanol dans le CO2 - supercritique,
Colloq. Inst. Nat. Rech. Agron., 1995, 71, p.179-182.

C. Vieville, J.W. Yoo, S. Pelet, Z. Mouloungui,
Synthesis of glycerol carbonate by direct carbonatation of glycerol in supercritical CO2 in the presence of zeolites and ion exchange resins
Catalysis Letters, 1998, 56(4), p. 245-247

J.W. Yoo, Z. Mouloungui,
Catalytic transcarbonatation of ethylene carbonate with glycerol for the co-generation of glycerol carbonate and ethylene glycol,
16th Canadian Symposium on Catalysis, Canada, 23 - 26 May 2000

V. Eychenne, S. Saiz, F. Trabelsi, F. Recasens,
Near-critical solvent extraction of wool with modified carbon dioxide - experimental results,
Journal of Supercritical Fluids, 2001, 21, p. 23-31

Y. Medina-Gonzalez, S. Thiebaud-Roux, P. de Caro, L. Hernandez-Ochoa, Z. Mouloungui,
The role of co-additive on epoxy resin prepolymers solubilization in supercritical CO2
Journal of Supercritical Fluids, 2006, 38, p. 13-17.

F. Gasc, M. Mazza , E. Rodier, JJ Letourneau, C.Cecutti, C.Vaca-Garcia , S. Thiebaud-Roux,
"Synthesis of Organic Carbonates in Supercritical Carbon Dioxide",
8th International Symposium on Supercritical Fluids, Kyoto, Japan, 5-8 November 2006

Y. Medina-Gonzalez, S. Thiebaud-Roux, P. de Caro, Z. Mouloungui,
�Supercritical CO2 � fatty acid esters and supercritical CO2 � multipolar systems : the role of co-additive on epoxy resin pre-polymers solubilisation�,
1st International Congress on Green Process Engineering, Toulouse, France, 24-26 April 2007

S. Thiebaud-Roux,
"Soy-based biosolvents : a real alternative to VOC-generating industrial solvents"
, International Seminar "Soybean � Renewable Resource for Industrial Non-Food Uses", Rio de Janeiro, Brazil, 11-12 April 2007 (Conf�rence invit�e)

Z. Mouloungui, S. Thiebaud-Roux, P. De Caro, V. Gerbaud,
Les voies de recherche sur les biosolvants�: Etat des lieux,
Journ�e Technique ADEME ��Biosolvants Solvants Environnement��, Paris, 27 mai 2008.

Contacts

2008-06-11T12:27:13+00:00

Directeurs

Marie-Elisabeth BORREDON

Contact : Sophie THIEBAUD-ROUX

Adresse

Laboratoire de Chimie Agro-Industrielle
UMR 1010 INRA/INPT-ENSIACET
ENSIACET
118 route de Narbonne
31077 Toulouse Cedex 04

T�l

05 62 88 57 01

Fax

05 62 88 57 30

Email

sophie.thiebaudroux@ensiacet.fr

Site Web

http://lca.ensiacet.fr

Brevets ICMCB

2008-01-25T15:11:13+00:00

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (FR)
Proc�d� de traitement des d�ch�ts par oxydation hydrothermale. Cansell F. France Brevet FR 2813599. 2002-03-08.
Extension : International Patent WO 0220414 (2002-03-14).

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (FR)
Proc�d� de d�marrage d'une installation de traitement des d�chets par oxydation hydrothermale. F. Cansell and M. Bottreau. France Brevet FR 2827272. 2003-01-17.
Extension : International Patent WO 03006388 (2003-01-23).

L'ELECTROLYSE (FR)
Device for transforming chemical structures in a fluid comprising a solvent and salts by ultrasonic action. D. Sentagnes, C. Aymonier, F. Berdeu and F. Cansell. US Patent US 6656436. 2003-12-02.
Extension du brevet original : France Brevet FR 2780902 (2000-01-14) / European Patent EP 1105353 (2000-01-20) / International Patent WO 0002821 (2000-01-20).

L'ELECTROLYSE (FR)
Method for transforming chemical structures in a fluid under pressure and in high temperature. D. Sentagnes, C. Aymonier, F. Berdeu and F. Cansell. US Patent US 6551517. 2003-04-22.
Extension du brevet original : France Brevet FR 2780986 (2000-01-14) / European Patent EP 1105352 (2000-01-20) / International Patent WO 0002820 (2000-01-20).

CENTRE NATIONAL DE LA RECHERCHER SCIENTIFIQUE (FR).
Proc�d� d'obtention d'un mat�riau composite f�rro�lectrique. Cansell F., Aymonier C., Huber C., Elissalde C. and Maglione M. France Brevet FR 2861088. 2005-04-22.
Extension : International Patent WO 2005038082 (2005-04-28).

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (FR)
Proc�d� de traitement de milieux aqueux comprenant des sels m�talliques de types nitrates ou sulfates. Cansell F., Gaudr� M. Num�ro de d�p�t 0406680.

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (FR)
Conversion hydrothermale de nitrate en acide nitrique. Cansell F.,Bottreau M. Num�ro de d�p�t 0406681

Brevets LGC

2008-01-25T15:10:47+00:00

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Oxydation contr�l�e des polysaccharides en gaz densifi�
M. Vignon, D. Samain, JS. Condoret, S. Montanari Brevet FR 0408402
Extension : International Patent PCT/Fr 0502002 demand�e en juillet 2005

Brevets RAPSODEE

2008-01-25T15:10:17+00:00

Proc�d� de pr�paration d'un compos� d'interaction de substances actives avec un support poreux par fluide supercritique.
B. Freiss, F. Marciacq, J. Fages, M. Sauceau, H. Lochard, JJ. Letourneau, et C. Joussot-Dubien. Brevet fran�ais n� 2 830 760. 2001, Europ�en EP 2.796.803 et mondial WO 03 043604.

Proc�d� de pr�paration d'un compos� d'interaction d'un d�riv� anilide avec un support poreux par fluide supercritique.
B. Freiss, F. Marciacq, J. Fages, M. Sauceau, H. Lochard, JJ. Letourneau et C. Joussot-Dubien. Brevet fran�ais n� 2 830 761. 2001 et mondial WO 03 030867.

ECOLE DES MINES ALBI-CARMAUX et CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (FR)

Proc�d� de production de particules.
J. Fages et JJ Letourneau. Brevet fran�ais n� 2 847 786. 2002.

Proc�d� de production de particules
J. Fages, JJ Letourneau et P Gonus. Brevet fran�ais n� 2 847 787. 2003 et mondial WO 04 047544.

Proc�d� de pr�paration de complexes mol�culaires.
Sauceau M., Lochard H., Freiss B. Brevet fran�ais n� 2 854 079. 2003 et mondial WO 04 096284.

Proc�d� d'enrobage de poudres.
M. Calderone, E Rodier et B . Freiss. Brevet fran�ais n� FR 2 874 836.

ARMINES

Fabrication de Dispersions Solides de Principes Actifs Pharmaceutiques par de Nouveaux Proc�d�s d�Extrusion.
Fages J. et Sauceau M. Demande de brevet FR05/515772005.

Production Scientifique ISM

2008-01-25T15:07:45+00:00

Y. Danten, T. Tassaing, M. Besnard
Vibrational Spectra of CO2-Electron Donor-Acceptor Complexes from Ab- Initio
J. Phys. Chem. A., 2002, 106, p. 11831

P. Lalanne, T. Tassaing, Y. Danten, F. Cansell, S. Tucker, M. Besnard
CO2-Ethanol interaction studied by vibrational spectroscopy in supercritical CO2
J. Phys. Chem. A, 2004, 108, p. 2617

T. Tassaing, R. Oparin, Y. Danten, M. Besnard
Water-CO2 interaction in supercritical CO2 as studied by infrared spectroscopy and vibrational frequency shift calculations
J. of Supercritical Fluids, 2005, 33, p. 85

S. Sala, N. Ventosa, T. Tassaing, M. Cano, Y. Danten, M. Besnard and J. Veciana
Synergistic enhancement of the solubility of hexamethylene-tetramine in subcritical CO2 ethanol mixtures studied by infrared spectroscopy
ChemPhysChem, 2005, 6, p. 58

Production Scientifique LGC

2008-01-25T15:07:13+00:00

Camy S, Condoret J.S
Dynamic modelling of a fractionation process for a liquid mixture using supercritical carbon dioxide
Chemical Engineering and Processing, 2001, Volume 40, Issue 6, 499-509

Kiriamiti H.K., Rascol E., Marty A., Condoret J.S.
Supercritical extraction of oil from oleic sunflower seeds
Chemical Engineering and Processing, 2002, Volume 41, Issue 8, 711-718

Kiriamiti H. K., Camy S., Gourdon C., Condoret J. S.
Pyrethrin extraction from pyrethrum flowers using carbon dioxide
The Journal of Supercritical Fluids, 2003,Volume 26, Issue 3, 193-200

Kiriamiti H., Camy S., Gourdon C., Condoret J.S.
Supercritical carbon dioxide extraction of pyrethrins from pale and oleoresin.
Journal of Agricultural and Food Chemistry, 51, 4 (2003).

S.Camy, J.-S. Pic, E. Badens, Condoret J.S.
Fluid phase equilibria of the reacting mixture in the dimethyl carbonate synthesis from supercritical CO2
The Journal of Supercritical Fluids, 2003,Volume 25, Issue 1,19-32

Ballivet-Tkatchenko D., Camy S., Condoret J.S.
Carbon dioxide, a solvent and synthon for green chemistry
Environmental Chemistry, Green Chemistry and Pollutants in Ecosystems (2005), chap 49, Eds E. Lichtfouse, J. Schwarzbauer, D. Robert, Springer ed.

S. Camy, J.S. Condoret
Modelling and experimental study of separators for co-solvent recovery in a supercritical extraction process
Journal of Supercritical Fluids, sous presse

Production Scientifique LFC

2008-01-25T15:06:37+00:00

X. Canet, A. Baylaucq et C. Boned
High-pressure (up to 140 MPa) dynamic viscosity of the methane + decane system
International Journal of Thermophysics, 23, 2002, p.1469-1486

C. Miqueu, B. Mendiboure, A. Graciaa, J. Lachaise
Modelling of the surface tension of pure components with the gradient theory of fluid interfaces: a simple and accurate expression for the influence parameters
Fluid Phase Equilibria, 207, 225-246 (2003)

A. Baylaucq, C.K. Z�berg-Mikkelsen, X. Canet et C. Boned
High-pressure (up to 140 Mpa) dynamic viscosity of the methane and toluene system: measurements and comparative study of some representative models
International Journal of Thermophysics , 24 , 3 , 2003 , p.621-638

C. Miqueu, B. Mendiboure, A. Graciaa, J. Lachaise
Modelling of the surface tension of binary and ternary mixtures with the gradient theory of fluid interfaces
Fluid Phase Equilibria, 218, 2, 189-203 (2004)

C. Boned, A. Allal, A. Baylaucq, C.K. Z�berg-Mikkelsen, D. Bessieres et S.E. Qui�ones-Cisneros.
Simultaneous free-volume modeling of self-diffusion coefficient and dynamic viscosity at high-pressure
Physical Review E: Statistical Physics, Nonlinear, and Soft Matter Physics 69, 2004, p.031203-1 011203-6

S.E. Qui�ones-Cisneros, C.K. Z�berg-Mikkelsen, A. Baylaucq et C. Boned
Viscosity modelling and prediction of reservoir fluids: from natural gas to heavy oils
International Journal of Thermophysics , 25, 5, 2004 , p.1353-1366

G. Galliero
Thermal diffusion in Lennard-Jones fluids in the frame of the law of the corresponding states
Fluid Phase Equilibria , 224 , 2004, p.13-22

Miqueu C., Mendiboure B., Graciaa A., Lachaise J.
Modeling of the surface tension of multicomponent mixtures with the gradient theory of fluid interfaces
Ind. Eng. Chem. Res., 44(9), 3321-3329 (2005).

Broseta D., Melean Y., Miqueu C.
Parachors of liquid/vapour systems : a set of critical amplitudes
Fluid Phase Equilibria, 233 (1), 86-95 (2005).

F. Plantier, A. Danesh, M. Sohrabi, JL Daridon, F. Gozalpour and A C. Todd.
Measurements of speed of sound for mixtures of methane + butane with a particular focus on the critical state
J. Chem. Eng. Data., 673-676 (50), (2005).

A. Baylaucq, C. Boned, X. Canet, C.K. Z�berg-Mikkelsen, S.E. Qui�ones-Cisneros, H. Zhou.
Dynamic viscosity modelling of methane + n-decane and methane + toluene mixtures: comparative study of some representative models
Petroleum Science and Technology, 23,(2005) , p.143-157.

D. Bessieres, T. Lafitte, J.L. Daridon, S. L. Randzio
High pressure thermal expansion of gases : measurements and calibration
Thermochimica Acta, 428, 25-30, (2005).

F. Plantier, JL Daridon
Speed of sound of 2-methylpentane, 2,3-dimethylpentane and 2,2,4-trimethylpentane from (293.15 to 373.15) K and up to 150 MPa
J. Chem. Eng. Data, sous presse.

Production Scientifique LCPO

2008-01-25T15:06:01+00:00

Bergeot V., Tassaing T., Besnard M., Cansell F. and Mingotaud A.-F.
Anionic ring-opening polymerization of -caprolactone in supercritical carbon dioxide : parameters influencing the reactivity.
J. Supercrit. Fluids 2004, vol. 28, n� 2-3, p. 249-261.

P. Chambon, E. Cloutet, H. Cramail
Synthesis of Core-shell polyurethane-polydimethylsiloxane particles in supercritical carbon dioxide
Macromolecules 37(16), 5856-5859 (2004).

P. Chambon, E. Cloutet, H. Cramail, T. Tassaing, M. Besnard
Synthesis of core-shell polyurethane-polydimethylsiloxane particles in cyclohexane and in supercritical carbon dioxide used as dispersant media : a comparative investigation
Polymer 46, 1057-1066 (2005).

Production Scientifique LATEP

2008-01-25T15:04:46+00:00

F. Marias, F. Mancini, F. Cansell, J. Mercadier
Energy Recovery for Supercritical Water Oxidation Process
Environmental Engineering Science, 2008, 25, N�1, 123-130

B. Khiari, F. Marias, F. Zagrouba and J. Vaxelaire
Transient mathematical modelling of a fluidized bed incinerator for sewage sludge
Journal of Cleaner Production, Volume 16, Issue 2, January 2008, Pages 178-191

F. Marias, F. Mancini, F. Cansell and J. Mercadier
Hydrothermal oxidation treatment of solid particles between 250 and 350 �C: Modelling and experiments
The Journal of Supercritical Fluids, Volume 41, Issue 3, July 2007, Pages 352-360

B. Khiari, F. Marias, F. Zagrouba and J. Vaxelaire
Incineration of a small particle of wet sewage sludge: A numerical comparison between two states of the surrounding atmosphere
Journal of Hazardous Materials, Volume 147, Issue 3, 25 August 2007, Pages 871-882

P. C�zac, J-P Serin, J-M Reneaume, J. Mercadier and G. Mouton
Elemental sulphur deposition in natural gas transmission and distribution networks
The Journal of Supercritical Fluids, In Press, Corrected Proof, Available online 19 November 2007

J. Mercadier, F. Marias, S. Vielcazals, F. Mancini, M. Bottreau, F. Cansell
Supercritical water oxidation of organic compounds. Experimental and numerical results
Environmental Engineering Science, 2007, 24, N�10, p1379-1388

P. Dutourni�, J. Mercadier, D. Mateos, F. Cansell
Hydrothermal oxidation treatment reactor: experimental and simulated study of a non anticipated phenomenon at the reactor inlet
Journal of Supercritical Fluids, 2007, 42, p234-240

F. Marias, F. Mancini, F. Cansell, J. Mercadier
Hydrothermal oxidation treatment of solid particles between 250�C and 350�C: Modelling and experiments
, Journal of Supercritical Fluids, 2007, 41, N�3, p 352-360

P. C�zac, J.P. Serin, J. Mercadier and G. Mouton,
Modelling solubility of solid sulphur in natural gas
, Chemical Eng. Journal, 2007, 133, 283-291.

F. Marias, S.Vielcazals, P. C�zac, J. Mercadier and F. Cansell,
Theoretical study of the expansion of supercritical water in a capillary device at the output of a hydrothermal oxidation process
The Journal of Supercritical Fluids, 2007, 40, 2, 208-217

S. Vielcazals, D. Mat�os, J. Mercadier, F. Marias, C. Marraud, M. Bottreau, F. Cansell,
Modelling for simulation of hydrothermal oxidation of organic compounds,
AICHE journal, 2006, 52, N�2, p 818 � 825

P. Dutourni�, J. Mercadier,
The Unsteady behaviour of hydrothermal oxidation reactor: theoretical and numerical studies near the critical point,
Journal of Supercritical Fluids, 2005, 35, p. 247-253.

D. Mateos, J. R. Portela, J. Mercadier, F. Marias, C. Marraud, F. Cansell,
New approach for kinetic parameters determination for hydrothermal oxidation reaction,
Journal of Supercritical Fluids 2005, 34, n� 1, p. 63-70.

P. Dutourni�, J. Mercadier,
Supercritical waste hydrothermal treatment modellisation of non stationary phenomena in a reactor,
Journal of Supercritical Fluids, 2004, 32, p. 153-160

P. Dutourni�, C. Aymonier, F. Cansell, J. Mercadier,
Experiments and Simulations of Time Dependant Phenomena in HTO Tubular Reactor.
Industrial & Engineering Chemistry Research, 2003, 42, p. 4708-4714)

Production Scientifique ICMCB

2008-01-25T15:04:05+00:00

Hegseth J., Garrabos Y., Nikolayev V., Lecoutre-Chabot C., Wunenburger R. and Beysens D.
Gas "wets" a solid wall in orbit.
Int. J. Thermophys. 2002, vol. 23, n� 1, p. 89-101.

Wunenburger R., Garrabos Y., Lecoutre-Chabot C., Beysens D., Hegseth J., Zhong F. and Barmat M.
Thermal response of a two-phase near-critical fluid in low gravity : strong gas overheating as due to a particular phase distribution.
Int. J. Thermophys. 2002, vol. 23, n� 1, p. 103-115.

Andrieu C., Beysens D., Nikolayev V. and Pomeau Y.
Coalescence of sessile drops.
J. Fluid Mech. 2002, vol. 453, p. 427-438.

Pessey V., Garriga R., Chevalier B., Weill F., Etourneau J. and Cansell F.
Control of particle growth by chemical transformation in supercritical CO2/ethanol mixtures.
J. Mater. Chem. 2002, vol. 12, n� 4, p. 958-965.

Le Neindre B. and Garrabos Y.
Scaled equations for the coexistence curve, the capillary constant and the surface tension of n-alkanes.
Fluid Phase Equilib. 2002, vol. 198, n� 2, p. 165-183.

Beysens D., Garrabos Y., Nikolayev V., Lecoutre-Chabot C., Delville J.-P. and Hegseth J.
Liquid-vapor phase separation in a thermocapillary force field.
Europhys. Lett. 2002, vol. 59, n� 2, p. 245-251.

Le Neindre B. and Garrabos Y.
Thermal conductivity of HFC-152a in the temperature range 300 to 455 K at pressures up to 55MPa.
High Temp. High Pressures 2002, vol. 34, p. 307-314.

Garrabos Y., Le Neindre B., Wunenburger R., Lecoutre-Chabot C. and Beysens D.
Universal scaling form of the equation of state of a critical pure fluid.
Int. J. Thermophys. 2002, vol. 23, n� 4, p. 997-1011.

Beysens D., Garrabos Y., Wunenburger R. and Lecoutre-Chabot C.
Can heat flow backward ? unusual thermal phenomena observed in near-critical fluids.
Physica A (Amsterdam) 2002, vol. 314, n� 1-4, p. 427-436.

Beysens D., Nikolayev V. and Garrabos Y.
Vapour spreading and the boiling crisis.
J. Phys. : Condens. Matter 2003, vol. 15, n� 1, p. S435-S442.

Bobet J.-L., Desmoulins-Krawiec S., Grigorova E., Cansell F. and Chevalier B.
Addition of nanosized Cr2O3 to magnesium for improvement of the hydrogen soprtion properties.
J. Alloys Compd. 2003, vol. 351, n� 1-2, p. 217-221.

Botella P., Frayret C., Jaszay T. and Delville M.-H.
Experimental study, via current-potential curves, of the anodic behavior of alloy C-276 and T60 titanium in chlorinated and oxygenated aqueous media under sub- to supercritical conditions.
J. Supercrit. Fluids 2003, vol. 25, n� 3, p. 269-278.

Frayret C., Jaszay T., Lestienne B. and Delville M.-H.
Development of a model for the anodic behavior of T60 titanium in chlorinated and oxygenated aqueous media. Application to the specific conditions of hydrothermal oxidation (1 MPa < pressure < 30 MPa, 20� C < temperature < 400� C).
Electrochim. Acta 2003, vol. 48, n� 12, p. 1685-1695.

Delville M.-H., Botella P., Jaszay T. and Frayret J. P.
Electrochemical study of corrosion in aqueous high pressure, high temperature media and measurements of materials corrosion rates : applications to the hydrothermal treatments of organic wastes by SCWO.
J. Supercrit. Fluids 2003, vol. 26, n� 2, p. 169-179.

Botella P., Cansell F., Jaszay T., Frayret J. P. and Delville M.-H.
Experimental set-up for electrochemical measurements in hydrothermal sub- and supercritical oxidation : polarization curves, determination of corrosion rates and evaluation of the degradability of reactors during hydrothermal treatments of aqueous wastes.
J. Supercrit. Fluids 2003, vol. 26, n� 2, p. 157-167.

Nikolayev V., Dejoan A., Garrabos Y. and Beysens D.
Fast heat transfer calculations in supercritical fluids versus hydrodynamic approach.
Phys. Rev. E : Stat. Phys. Plasmas Fluids Relat. Interdiscip. Topics 2003, vol. 67, n� 6, p. 061202 (1-11).

Dutourni� P., Aymonier C., Cansell F. and Mercadier J.
Experiments and simulations of time-dependant phenomena in a hydrothermal oxidation tubular reactor.
Ind. Eng. Chem. Res. 2003, vol. 42, n� 20, p. 4708-4714.

Nikolayev V. and Beysens D.
Equation of motion of the triple contact line along an inhomogeneous surface.
Europhys. Lett. 2003, vol. 64, n� 6, p. 763-768.

Cansell F., Aymonier C. and Loppinet-Serani A.
Review on materials science and supercritical fluids.
Curr. Opin. Solid State Mater. Sci. 2003, vol. 7, n� 4-5, p. 331-340.

Desmoulins-Krawiec S., Aymonier C., Loppinet-Serani A., Weill F., Gorsse S., Etourneau J. and Cansell F.
Synthesis of nanostructured materials in supercritical ammonia : nitrides, metals and oxides.
J. Mater. Chem. 2004, vol. 14, n� 1, p. 228-232.

Nahre R., Beysens D. and Nikolayev V.
Contact line dynamics in drop coalescence and spreading.
Langmuir 2004, vol. 20, n� 4, p. 1213-1221.

Lalanne P., Tassaing T., Danten Y., Cansell F., Tucker C. and Besnard M.
CO2-Ethanol interaction studied by vibrational spectroscopy in supercritical CO2.
J. Phys. Chem. A 2004, vol. 108, n� 14, p. 2617-2624.

Frayret C., Botella P., Jaszay T. and Delville M.-H.
Titanium dissolution-passivation in highly chloridic and oxygenated aqueous solutions.
J. Electrochem. Soc. 2004, vol. 151, n� 10, p. B543-B550.

Nikolayev V., Beysens D. and Garrabos Y.
Crise d'�bullition: inhibition du d�tachement de la bulle de vapeur par la force de recul.
Mec. Ind. (Paris) 2004, vol. 5, n� 5, p. 553-558.

Loppinet-Serani A., Aymonier C., Desmoulins-Krawiec S., Weill F. and Cansell F.
Les fluides supercritiques: un nouveau milieu r�actionnel pour la synth�se de nanoparticules.
Recents Prog. Genie Procedes 2004, n� 91, p. (1-5).

Mateos D., Portela J. R., Mercadier J., Marias F., Marraud C. and Cansell F.
New approach for kinetic parameters determination for hydrothermal oxidation reaction.
J. Supercrit. Fluids 2005, vol. 34, n� 1, p. 63-70.

Aymonier C., Elissalde C., Reveron H., Weill F., Maglione M. and Cansell F.
Supercritical fluid technology of nanoparticle coating for new ceramic materials
J. Nanosci. Nanotechnol. 2005, vol. 5, n� 6, p. 980-983.

Elissalde C., Reveron H., Aymonier C., Michau D., Cansell F. and Maglione M.
The ferroelectric transition temperature as an intrinsic probe for sintered nanocrystalline BaTiO3 synthesized under supercritical conditions.
Nanotechnology 2005, vol. 16, n� 6, p. 797�802.

Reveron H., Aymonier C., Loppinet-Serani A., Elissalde C., Maglione M. and Cansell F.
Single-step synthesis of well-crystallized and pure barium titanate nanoparticles in supercritical fluids.
Nanotechnology 2005, vol. 16, n� 8, p. 1137-1143.

Emelianov V. M., Lednev A. K., Polezhaev V. I., Ivanov A. I., Putin G. F., Zyuzgin A. V., Beysens D.and Garrabos Y.
Convection and heat transfer experiments in supercritical fluid under microgravity: from MIR to ISS.
Microgravity Sci. Technol. 2005, vol. 16, n� 1, p. 164-169.

Besnard M., Tassaing T., Danten Y., Andanson J.M., Soetens J.C., Cansell F., Loppinet-Serani A., Reveron H., Aymonier C.
Bringing together fundamental and applied science: The supercritical fluids route
J. Mol. Liquid, sous presse.

Reveron H., Elissalde C., Aymonier C.,Maglione M., Cansell F.
Continuous synthesis of well-crystallized BST nanoparticles under supercritical conditions and its ferroelectric properties
J. Nanosci. Nanotechnol, sous presse.

Vielcazals S., Mateos D., Mercadier J., Marias F., Marraud C., Bottreau M., Cansell F.
Modeling and simulation of hydrothermal oxidation of organic compounds
AIChE Journal, sous presse.

Equipements

2008-01-25T14:59:22+00:00

2 cellules d��quilibres agit�es � volume variables

Caract�ristiques :

Cellule 1

Volume maximum :	500 cm3
Pression maximum :	500 bar
Temp�rature maximum :	200�C

Cellule 2

Volume maximum :	5000 cm3
Pression maximum :	200 bar
Temp�rature maximum :	200�C

1 r�acteur HP agit� (haut et bas) coupl� � un s�parateur

Caract�ristiques :

Volume du r�acteur :	1000 cm3
Pression maximum :	300 bar
Temp�rature maximum :	200�C

2 Chromatographie Phase Gaz (CPG)

Caract�ristiques :

Injection normale ou grand volume
D�tecteur FPD ou FID
Passeur automatique

1 DSC (Differential Scanning Calorimetry)

Caract�ristiques :

Pression :	atmosph�rique
Temp�rature :	-170�C � 700�C

Th�matiques

2008-01-25T14:51:24+00:00

R�action chimique � Oxydation hydrothermale

Simulation des r�acteurs � l��chelle macroscopique

Elaboration et mise en forme de mat�riaux finement divis�s

Mesure et mod�lisation de la solubilit� en FSC

Proc�d�s et r�actions en milieu supercritique

Thermodynamique

Contacts

2008-01-25T14:39:09+00:00

Contact

Jacques Mercadier

Adresse

Laboratoire Thermique Energ�tique et Proc�d� de Pau (LaTEP)
ENSGTI - Universit� de Pau et des Pays de l�Adour
rue Jules Ferry, BP 7511, 64075, Pau Cedex

Tel

33 5 59 40 78 00

Fax

33 5 59 40 78 01

E-mail

jacques.mercadier@univ-pau.fr

Web site

http://ensgti.univ-pau.fr/